Browsing by Subject "Torquoselectivity"
Now showing items 1-2 of 2
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Selectivity in the Interrupted Nazarov Reaction
Three allenyl vinyl ketones (AVKs) underwent Lewis acid-mediated Nazarov cyclization in the presence of a variety of dienes. Products arising from the (4+3)- and (3+2)-cycloaddition to the oxyallyl cation intermediate of ... -
Stereochemical Aspects in the Interrupted Nazarov Reaction of Allenyl Vinyl Ketones: A Computational Study
(2014-07-24)Transition state models are often invoked to explain stereochemical outcomes in chemical reactions. The relevance of these models to correctly predict these outcomes can be further validated by studying reactions where ...
